Хрусталев Виктор Николаевич

Девиз по жизни:

Жизнь ставит цели науке; наука освещает путь жизни.

Биография

• 993 — с отличием окончил Московский институт тонкой химической технологии им. М.В.Ломоносова по специальности физика и химия твердого тела.
• 1993-2017 — сотрудник Лаборатории рентгеноструктурных исследований Института элементоорганических соединений им. А.Н.Несмеянова Российской академии наук (ИНЭОС РАН).
• 2000 — защитил диссертацию на соискание ученой степени кандидата химических наук по специальности 02.00.01 – неорганическая химия на тему: «Синтез и рентгеноструктурное исследование перренатов элементов III группы Периодической системы».
• 2008 — защитил диссертацию на соискание ученой степени доктора химических наук по специальностям 02.00.04 – физическая химия и 02.00.08 – химия элементоорганических соединений на тему: «Структурные аспекты химии неклассических соединений кремния, германия и олова».
• 2013-2014 — исполняющий обязанности заведующего Лабораторией рентгеноструктурных исследований Института элементоорганических соединений имени А. Н. Несмеянова Российской академии наук.
• 2015-н.в. — заведующий кафедрой неорганической химии Российского университета дружбы народов.
• 2017-н в. — директор Объединенного института химических исследований РУДН.

Преподавание

• читает в Российском университете дружбы народов курсы «Физические методы исследования веществ и материалов», «Актуальные задачи современной химии», «Общая и неорганическая химия»
• с 2006 года Виктор Хрусталев обучает основам метода рентгеноструктурного анализа бакалавров и магистров Нью-Мексиканского Высокогорного университета в США (New Mexico Highlands University, Las Vegas, NM USA); с 2007 года – бакалавров, магистров и аспирантов Бакинского государственного университета в республике Азербайджан (г. Баку)

• S.L.Fraser, M.Yu.Antipin, V.N.Khrustalev, V.V.Grushin, “Molecular fluoro palladium complexes. The first structurally characterized Pd-F bond”, Journal of American Chemical Society, 1997, 119, 4769.
• N.B.Chernyshova, D.V.Tsyganov, V.N.Khrustalev, M.M.Raihstat, L.D.Konyushkin, R.V.Semenov, M.N.Semenova, V.V.Semenov, “Synthesis and antimitotic properties of ortho-substituted polymethoxydiarylazolopyrimidines”, ARKIVOC, 2017, 151-165.
• N.N.Zemlyansky, I.V.Borisova, V.N.Khrustalev, Yu.A.Ustynyuk, M.S.Nechaev, V.V.Lunin, J.Barrau, G.Rima, “New stable germylenes, stannylenes, and related compounds. 1. Stable germanium(II) and tin(II) compounds M(OCH2CH2NMe2)2 (M = Ge, Sn) with intramolecular coordination metal-nitrogen bonds. Synthesis and structure”, Organometallics, 2003, 22, 1675-1681.
• J.L.Sessler, E.Katayev, G.D.Pantos, P.Scherbakov, M.D.Reshetova, V.N.Khrustalev, V.M.Lynch, Yu.A.Ustynyuk, “Fine tuning the anion binding properties of 2,6-diamidopyridine dipyrromethane hybrid macrocycles”, Journal of the American Chemical Society, 2005, 127, 11442-11446.
• E.A.Katayev, G.D.Pantos, M.D.Reshetova, V.N.Khrustalev, V.M.Lynch, Yu.A.Ustynyuk, J.L.Sessler, “Anion induced synthesis and combinatorial selection of polypyrrolic macrocycles”, Angewandte Chemie, International Edition, 2005, 44, 7386-7390.
• V.N.Khrustalev, I.A.Portnyagin, I.V.Borisova, N.N.Zemlyansky, Yu.A.Ustynyuk, M.Yu.Antipin, M.S.Nechaev, “Donor-stabilized germyl cations. Stable pentacoordinate germanium chloride [PhGe(OCH2CH2NMe2)2][Cl]”, Organometallics, 2006, 25, 2501-2504.
• V.N.Khrustalev, K.A.Krasnov, “Weak interactions in 1,3-dimethyl-5-arylmethyl-5-cytisylmethylbarbituric acids. Unusually steady intramolecular organic “sandwich” complexes”, Journal of Molecular Structure, 2007, 828, 188-194.
• A.S.Burlov, V.G.Vlasenko, P.V.Dorovatovskii, Ya.V.Zubavichus, V.N.Khrustalev, “Crystal structure of bis{1-phenyl-3-methyl-4-[(quinolin-3-yl)iminomethyl-κN]-1H-pyrazol-5-olato-κO}zinc methanol 2.5-solvate from synchrotron X-ray diffraction”, Acta Crystallographica, 2017, E73, 1208-1212.
• T.A.Albright, P.I.Dosa, T.N.Grossmann, V.N.Khrustalev, O.A.Oloba, R.Padilla, R.Paubelle, A.Stanger, T.V.Timofeeva, K.P.C.Vollhardt, “Photo-thermal haptotropism in cyclopentadienylcobalt complexes of linear phenylenes: intercyclobutadiene metal migration”, Angewandte Chemie International Edition, 2009, 48, 9853-9857.
• V.N.Khrustalev, S.O.Kostenko, M.I.Buzin, A.A.Korlyukov, Y.V.Zubavichus, M.A.Kurykin, M.Yu.Antipin, “Highly flexible molecule “chameleon”: reversible thermochromism and phase transitions in solid copper(II) diiminate Cu[CF3-C(NH)-CF=C(NH)-CF3]2”, Inorganic Chemistry, 2012, 51, 10590-10602.
• V.N.Khrustalev, Sh.R.Ismaylova, R.R.Aysin, Zh.V.Matsulevich, V.K.Osmanov, A.S.Peregudov, A.V.Borisov, “Perpendicular versus coplanar conformation of the SeCl2 moiety in T-shaped selenyl chloride adducts – propeller-like free rotation in solution”, European Journal of Inorganic Chemistry, 2012, 5456-5460.
• C.A.Bauer, S.C.Jones, T.L.Kinnibrugh, P.Tongwa, R.A.Farrell, A.Vakil, T.V.Timofeeva, V.N.Khrustalev, M.D.Allendorf, “Homo- and heterometallic luminescent 2-D stilbene metal-organic frameworks”, Dalton Transactions, 2014, 43, 2925-2935.
• V.N.Khrustalev, Zh.V.Matsulevich, Ju.M.Lukiyanova, R.R.Aysin, A.S.Peregudov, L.A.Leites, A.V.Borisov, “A facile route for stabilizing highly reactive ArTeCl species via the formation of T-shaped tellurenyl chloride adducts: quasi-planar zwitterionic [HPy*]TeCl2 and [HPm*]TeCl2; Py* = 2-pyridyl, Pm* = 2-(4,6-dimethyl)pyrimidyl”, European Journal of Inorganic Chemistry, 2014, 3582-3586.
• K.A.Krasnov, V.N.Khrustalev, “Diastereoselective T-reaction of 1-alkyl-(5-nitro-2-N-morpholino-benzyliden)barbituric acids in the solid state: synthesis of 1-alkyl-2,4,6-trioxoperhydropyrimidino-5-spiro-10’-(7’-nitro-1’,3’,4’,9’,10’,10а’-hexahydro-2’-oxa)-4a’-aza-phenanthrenes and their 2’-thia analogues”, Crystal Growth & Design, 2014, 14, 3975-3982.
• I.Davydenko, S.Barlow, R.Sharma, S.Benis, J.Simon, T.G.Allen, M.W.Cooper, V.N.Khrustalev, E.V.Jucov, R.Castañeda, C.Ordonez, Z.Li, S.-H.Chi, S.-H.Jang, T.C.Parker, T.V.Timofeeva, J.W.Perry, A.K.-Y.Jen, D.J.Hagan, E.W. van Stryland, S.R.Marder, “Facile incorporation of Pd(PPh3)2Hal substituents into polymethines, merocyanines, and perylene diimides as a means of suppressing intermolecular interactions”, Journal of the American Chemical Society, 2016, 138, 10112-10115.
• A.N.Bilyachenko, M.M.Levitsky, A.I.Yalymov, A.A.Korlyukov, V.N.Khrustalev, A.V.Vologzhanina, L.S.Shul’pina, N.S.Ikonnikov, A.E.Trigub, P.V.Dorovatovskii, X.Bantreil, F.Lamaty, J.Long, J.Larionova, I.E.Golub, E.S.Shubina, G.B.Shul’pin, “Cage-like Fe,Na-germsesquioxanes: structure, magnetism, and catalytic activity”, Angewandte Chemie, International Edition, 2016, 55, 15360-15363.
• F.I.Zubkov, D.N.Orlova, V.P.Zaytsev, A.A.Voronov, E.V.Nikitina, V.N.Khrustalev, R.A.Novikov, M.Krasavin, A.V.Varlamov, “Short approach to pyrrolopyrazino-, pyrrolodiazepino-isoindoles and their benzo analogues via the IMDAF reaction”, Current Organic Synthesis, 2017, accepted.
• A.V.Krivoshein, S.V.Lindeman, T.V.Timofeeva, V.N.Khrustalev, “Racemic and enantiopure forms of 3-ethyl-3-phenylpyrrolidin-2-one adopt very different crystal structures”, Chirality, 2017, DOI: 10.1002/chir.22735.
• A.N.Bilyachenko, A.N.Kulakova, M.M.Levitsky, A.A.Korlyukov, V.N.Khrustalev, A.V.Vologzhanina, A.A.Titov, P.V.Dorovatovskii, L.S.Shul’pina, F.Lamaty, X.Bantreil, B.Villemejeanne, C.Ruiz, J.Martinez, E.S.Shubina, G.B.Shul’pin, “Ionic complexes of tetra- and nonanuclear cage Cu(II)-phenylsilsesquioxanes: synthesis and high activity in oxidative catalysis”, ChemCatChem, 2017, DOI: 10.1002/cctc.201701063.
• S.N.Bejagam, M.S.Fonari, B.B.Averkiev, V.N.Khrustalev, J.Lindline, T.V.Timofeeva, “Adducts of N-heterocyclic drugs, niacin, allopurinol, and amiloride, with 2,4-pyridinedicarboxylic acid coformer”, Crystal Growth & Design, 2017, DOI: 10.1021/acs.cgd.7b00542.
• O.V.Kovalchukova, P.V.Dorovatovskii, Ya.V.Zubavichus, K.V.Bozhenko, A.N.Utenyshev, R.Alabada, O.V.Volyansky, V.N.Khrustalev, “An unusual coordination of a 4-azopyrazol-5-one heterocyclic derivative with metals. Synthesis, X-ray studies, spectroscopic characteristics, and theoretical modeling”, Inorganica Chimica Acta, 2017, 466, 266-273.
• F.I.Zubkov, E.A.Kvyatkovskaya, E.V.Nikitina, P.N.-A.Amoyaw, V.V.Kouznetsov, V.A.Lazarenko, V.N.Khrustalev, “Comment on “An unexpected formation of the novel 7-oxa-2-azabicyclo[2.2.1]hept-5-ene skeleton during the reaction of furfurylamine with maleimides and their bioprospection using a zebrafish embryo model” by C.E.Puerto Galvis and V.V.Kouznetsov, Org. Biomol. Chem., 2013, 11, 407”, Organic & Biomolecular Chemistry, 2017, 15, 6447-6450.
• O.V.Kovalchukova, M.A.Ryabov, P.V.Dorovatovskii, Ya.V.Zubavichus, A.N.Utenyshev, D.N.Kuznetsov, O.V.Volyansky, V.K.Voronkova, V.N.Khrustalev, “Synthesis and characterization of a series of novel N-heterocyclic azo-colorants derived from 4-azo-pyrazol-5-one as free ligands and metal complexes”, Polyhedron, 2017, 121, 41-52.
• V.G.Nenajdenko, A.V.Shastin, V.M.Gorbachev, S.V.Shorunov, V.M.Muzalevskiy, A.I.Lukianova, P.V.Dorovatovskii, V.N.Khrustalev, “Copper-catalyzed transformation of hydrazones into halogenated azabutadienes, versatile building blocks for organic synthesis”, ACS Catalysis, 2017, 7, 205-209.
• S.V.Zubkevich, S.Ch.Gagieva, V.A.Tuskaev, P.V.Dorovatovskii, V.N.Khrustalev, A.I.Sizov, B.M.Bulychev, “Synthesis and reactivity in ethylene oligomerization by heteroscorpionate dibromonickel(II) complexes”, Inorganica Chimica Acta, 2017, 458, 58-67.
• N.A.Kolosov, V.A.Tuskaev, S.Ch.Gagieva, I.V.Fedyanin, V.N.Khrustalev, O.V.Polyakova, B.M.Bulychev, “Vanadium (V) and titanium (IV) compounds with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinolines: Synthesis, structure and catalytic behaviors to olefin polymerization”, European Polymer Journal, 2017, 87, 266-276.
• Yu.Samoilichenko, V.Kondratenko, M.Ezernitskaya, K.A.Lyssenko, A.S.Peregudov, V.N.Khrustalev, V.I.Maleev, M.Moskalenko, M.North, A.Tsaloev, Z.T.Gugkaeva, Yu.N.Belokon, “A mechanistic study of the Lewis acid-Brønsted base-Brønsted acid catalysed asymmetric Michael addition of diethyl malonate to cyclohexenone”, Catalysis Science & Technology, 2017, 7, 90-101.
• M.V.Makarov, E.Yu.Rybalkina, L.V.Anikina, S.A.Pukhov, S.G.Klochkov, D.V.Mischenko, M.E.Neganova, V.N.Khrustalev, Z.S.Klemenkova, V.K.Brel, “1,5-Diaryl-3-oxo-1,4-pentadienes based on (4-oxopiperidin-1-yl)(aryl)methyl phosphonate scaffold: synthesis and antitumor properties”, Medicinal Chemistry Research, 2017, 26, 140-152.
• T. van Nguyen, T.A.Le, A.T.Soldatenkov, T.A.D.Thi, T.T. van Tran, N.Ya.Esina, V.N.Khrustalev, “Crystal structure of 22,24,25-trimethyl-8,11,14-trioxa-25-azatetra-cyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaen-23-one”, Acta Crystallographica, 2017, E73, 118-121.
• K.A.Krasnov, P.V.Dorovatovskii, Ya.V.Zubavichus, T.V.Timofeeva, V.N.Khrustalev, “Hydride transfer reactions of 5-(2-alkoxybenzylidene) barbituric acids: Synthesis of 2,4,6-trioxoperhydropyrimidine-5-spiro-3′-chromanes”, Tetrahedron, 2017, 73, 542-549.
• V.T.Nguyen, E.A.Sorokina, A.V.Listratova, L.G.Voskressensky, N.N.Lobanov, P.V.Dorovatovskii, Ya.V.Zubavichus, V.N.Khrustalev, “Ring-expansion synthesis and crystal structure of dimethyl 4-ethyl-1,4,5,6,7,8-hexahydroazonino[5,6-b]indole-2,3-dicarboxylate”, Acta Crystallographica, 2017, E73, 338-340.
• L.G.Voskressensky, T.N.Borisova, M.D.Matveeva, V.N.Khrustalev, A.A.Titov, A.V.Aksenov, S.V.Dyachenko, A.V.Varlamov, “A facile synthesis of 1-oxo-pyrrolo[2,1-a]isoquinolines”, Tetrahedron Letters, 2017, 58, 877-879.
• I.G.Mamedov, Y.V.Mamedova, V.N.Khrustalev, M.R.Bayramov, A.M.Maharramov, “Dependence of biological activities of some chalcone derivatives from the molecular structure”, Indian Journal of Chemistry, 2017, 56B, 192-196.
• L.G.Voskressensky, A.A.Titov, M.Dzhankaziev, T.N.Borisova, M.Kobzev, P.V.Dorovatovskii, V.N.Khrustalev, A.V.Aksenov, A.V.Varlamov, “First synthesis of heterocyclic allenes – benzazecine derivatives”, New Journal of Chemistry, 2017, 41, 1902-1904.
• E.A.Kvyatkovskaya, V.P.Zaytsev, F.I.Zubkov, P.V.Dorovatovskii, Ya.V.Zubavichus, V.N.Khrustalev, “Interaction between maleic acid and N-R-furfurylamines: crystal structure of 2-methyl-N-[(5-phenylfuran-2-yl)methyl]propan-2-aminium (2Z)-3-carboxyacrylate and N-[(5-iodofuran-2-yl)methyl]-2-methylpropan-2-aminium (2Z)-3-carboxyprop-2-enoate”, Acta Crystallographica, 2017, E73, 515-519.
• A.A.Petrov, E.A.Goodilin, A.B.Tarasov, V.A.Lazarenko, P.V.Dorovatovskii, V.N.Khrustalev, “Formamidinium iodide: crystal structure and phase transitions”, Acta Crystallographica, 2017, E73, 569-572.
• A.I.Yalymov, A.N.Bilyachenko, M.M.Levitsky, A.A.Korlyukov, V.N.Khrustalev, L.S.Shul’pina, P.V.Dorovatovskii, M.A.Es’kova, F.Lamaty, X.Bantreil, B.Villemejeanne, J.Martinez, E.S.Shubina, Yu.N.Kozlov, G.B.Shul’pin, “High catalytic activity of heterometallic (Fe6Na7 and Fe6Na6) cage silsesquioxanes in oxidations with peroxides”, Catalysts, 2017, 7, 101-118.
• G.Chesnokov, M.Topchiy, P.Dzhevakov, P.Gribanov, A.Tukov, V.N.Khrustalev, A.Asachenko, M.S.Nechaev, “Eight-membered-ring diaminocarbenes bearing naphthalene moiety in the backbone: DFT studies, synthesis of amidinium salts, generation of free carbene, metal complexes, and solvent-free copper catalyzed azidealkyne cycloaddition (CuAAC) reaction”, Dalton Transactions, 2017, 46, 4331-4345.
• A.N.Bilyachenko, A.N.Kulakova, M.M.Levitsky, A.A.Petrov, A.A.Korlyukov, L.S.Shul’pina, V.N.Khrustalev, P.V.Dorovatovskii, A.V.Vologzhanina, U.S.Tsareva, I.E.Golub, E.S.Gulyaeva, E.S.Shubina, G.B.Shul’pin, “Unusual tri-, hexa-, and nonanuclear Cu(II) cage methylsilsesquioxanes: synthesis, structures, and catalytic activity in oxidations with peroxides”, Inorganic Chemistry, 2017, 56, 4093-4103.
• S.A.Rzhevskii, V.B.Rybakov, V.N.Khrustalev, E.V.Babaev, “Reactions of 5-indolizyl lithium compounds with some bielectrophiles”, Molecules, 2017, 22, 661-669.
• A.V.Astakhov, O.V.Khazipov, A.Yu.Chernenko, D.V.Pasyukov, A.S.Kashin, E.G.Gordeev, V.N.Khrustalev, V.M.Chernyshev, V.P.Ananikov, “A new mode of operation of Pd-NHC systems studied in a catalytic Mizoroki–Heck reaction”, Organometallics, 2017, 36, 1981-1992.
• Л.Г. Воскресенский, А.А. Титов, Р. Самавати, М.С. Кобзев, П.В. Дороватовский, В.Н. Хрусталев, Х.Ч. Хонг, Т.А.Д. Тхи, Т.Н. Ван, Е.А. Сорокина, А.В. Варламов, “Синтез 1-тетразолилзамещенных 2,3,4,9-тетрагидро-1H-β-карболинов и их трансформации с участием активированных алкинов”, Химия гетероциклических соединений, 2017, 53(5), 575-581.
• D.P.Zarezin, V.N.Khrustalev, V.G.Nenajdenko, “Diastereoselectivity of azido-Ugi reaction with secondary amines. Stereoselective synthesis of tetrazole derivatives”, Journal of Organic Chemistry, 2017, 82(12), 6100-6107.
• A.S.Burlov, E.I.Mal’tsev, V.G.Vlasenko, D.A.Garnovskii, A.V.Dmitriev, D.A.Lypenko, A.V.Vannikov, P.V.Dorovatovskii, V.A.Lazarensko, Ya.V.Zubavichus, V.N.Khrustalev, “Synthesis, structure, photo- and electroluminescent properties of bis{(4-methyl-N-[2-[(E)-2-pyridyliminomethyl]phenyl)]benzenesulfonamide}zinc(II)”, Polyhedron, 2017, 133, 231-237.
• V.P.Zaytsev, E.L.Revutskaya, T.V.Nikanorova, E.V.Nikitina, P.V.Dorovatovskii, V.N.Khrustalev, N.Z.Yagafarov, F.I.Zubkov, A.V.Varlamov, “An intramolecular Diels–Alder furan (IMDAF) approach towards the synthesis of isoindolo[2,1-a]quinazolines and isoindolo[1,2-b]quinazolines”, Synthesis, 2017, 49, 3749-3767.
• O.V.Rudnitskaya, E.K.Kultyshkina, E.V.Dobrokhotova, V.S.Podvoyskaya, P.V.Dorovatovskii, V.A.Lazarenko, Ya.V.Zubavichus, V.N.Khrustalev, “The Synthesis,Characterization, and Structure of (ThioH)2[OsХ6] (Х = Cl, Br)”, Polyhedron, 2017, 134, 114-119.
• В.П. Шевердов, М.А. Марьясов, В.В. Давыдова, О.Е. Насакин, П.В. Дороватовский, В.Н. Хрусталев, “Реакция метил-2,4-диоксобутаноатов с тетрацианоэтиленом”, Журнал общей химии, 2017, 87, 1097-1101.